Electric field gradients at111Cd in binary oxides
- 21 June 1993
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 5 (25) , 4111-4124
- https://doi.org/10.1088/0953-8984/5/25/002
Abstract
The electric field gradients (EFGs) of 111Cd at substitutional sites in binary oxides of different crystal structures obtained in perturbed angular correlation (PAC) experiments are collected and compared to point charge model (PCM) calculations. The error of the calculated EFGs is estimated from the experimental error in the crystal parameters. The PCM seems to be a good approximation for oxides with bond lengths exceeding d approximately=2.1 AA and here the theoretical shielding factor gamma infinity can be used. The application of radially dependent shielding factors for d<or=2.1 AA where covalent bonding prevails is discussed.Keywords
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