Synthesis of the first example of a cyclometallated ortho-nitrophenyl complex. X-Ray molecular structure of carbonyl(chloro)bis(o-nitrophenyl-C,O)rhodium
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 1004-1005
- https://doi.org/10.1039/c39850001004
Abstract
The complex [RhCl(CO)2]2 reacts at room temperature with [Hg(2-C6H4NO2)2](1:2) to give metallic mercury and the complex [[graphic ommitted])2Cl(CO)] whose crystal structure shows an octahedral co-ordination with one oxygen atom of each nitrophenyl ligand co-ordinated to the rhodium atom.Keywords
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