Reactions of radical anions. Part VII. Disproportionation of the radical anion of acenaphthenequinone
- 1 January 1969
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society B: Physical Organic
- p. 546-547
- https://doi.org/10.1039/j29690000546
Abstract
An e.s.r. study of the disproportionation of the radical-anion of acenaphthenequinone, 2(AQ–·M+) [graphic omitted] (AQ2–2M+)+ AQ gives the results at –10° for Li+, Na+, K+, Rb+, and Cs+: K1, 38,200, 1110, 86·5, 35·9, and 10,800; ΔG1a°, –5·8, –4·0, –2·3, –2·0, and –4·7 kcal. mole–1; ΔH1a°, –13·8, –5·8, –7·3, –6·9, and –6·7 kcal. mole–1; ΔS1a°, –30·5, –6·9, –19·0, –18·5, and –7·6 cal. deg.–1 mole–1 respectively.Keywords
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