Stereoselective Transformation of Baylis-Hillman Adducts into (3E)-3-(Alkoxymethyl)alk-3-en-2-ones

Abstract
The pure (3E)-3-(methoxymethyl)alk-3-en-2-ones and (3E)-3-(ethoxymethyl)alk-3-en-2-ones are formed in the acid induced reaction of 4-hydroxy-3-methylenealkan-2-ones with methanol and ethanol, respectively.

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