Cobalt nuclear resonance measurements of rate processes and a system in equilibrium

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Abstract
The intensities of cobalt nuclear resonance spectra have been used to study the rate of exchange at various temperatures between ethylenediamine and the cobalt hexammine (III) ion. The variation of the relative intensities of the two lines from sodium cobaltinitrite solutions with temperature has been studied and interpreted in terms of an isomerization equilibrium. The rates of both electron and ligand exchange in solutions of cobalt complexes have been found to be slow.

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