Oxygen atom transfer in the oxidation of triphenylphosphine by µ-oxo-bis[phthalocyaninatoiron(III)]
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 549-550
- https://doi.org/10.1039/c39830000549
Abstract
It has been shown that µ-oxo-bis[phthalocyaninatoiron(III)] can oxidize triphenylphosphine to triphenylphosphine oxide in the presence of pyridine under mild conditions, resulting in the formation of the corresponding FeII-bis adduct; this reaction is a rare example of O atom transfer by a µ-oxo FeIII oligomer.Keywords
This publication has 0 references indexed in Scilit: