A robust, porous, cationic silver(i) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 49.66 netElectronic supplementary information (ESI) available: experimental details, XPRD patterns, TGA curves and IR spectra. See http://www.rsc.org/suppdata/cc/b4/b404269g/
- 13 August 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 18,p. 2058-2059
- https://doi.org/10.1039/b404269g
Abstract
The reactions of silver(I) salts with 3,5-diphenyl-1,2,4-triazole result in three-dimensional, porous, cationic metal–organic frameworks based on novel 6-connected, trigonal-prismatic, pentanuclear silver-triazolate clusters, interconnected by linear N–Ag–N linkers; this robust water- and organic-insoluble structure exhibits both nonpolar-solvent adsorption and anion-exchange properties.Keywords
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