The Relation of Fluidity to Volume in Organic Liquids
- 1 March 1940
- journal article
- conference paper
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 11 (3) , 192-202
- https://doi.org/10.1063/1.1712757
Abstract
The Batschinski expression relating the fluidity of a compound to the specific volume at various temperatures is inadequate in the cases of associated compounds and those of high molecular weight. A modification, herein given, consists of the introduction of a correction term. The new expression, which relates linearly the fluidity and the corrected molecular free volume, has universal applicability and it holds with a high degree of precision. The constants of the new relationship are related to the complexity of the compounds in homologous series. From the constants given, the fluidity of undetermined members of the homologous series studied can be calculated if the density is known at that temperature.This publication has 2 references indexed in Scilit:
- III. On the relations between the viscosity (internal friction) of liquids and their chemical nature.—Part IIPhilosophical Transactions of the Royal Society A, 1897
- X. Bakerian lecture .—On the Relations between the viscosity (internal friction) of liquids and their chemical naturePhilosophical Transactions of the Royal Society of London. (A.), 1894