Addition of Nitrogen Functionality to Exocyclic Alkenes: A New Procedure for Azidoselenenylation
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (05) , 419-421
- https://doi.org/10.1055/s-1992-21366
Abstract
The reaction of exocyclic alkenes with N-phenylselenophthalimide and azidotrimethylsilane in dichloromethane affords ß-phenylselno azides. Products resulting from the elimination of either the azido or phenylseleno group are not observed under these conditions. Anti-Markovnikov regioselectivity is enhanced by the addition of tetrabutylammonium fluoride to the reaction.Keywords
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