A NEW TRICYCLOUNDECANE INTERMEDIATE IN AN ADAMANTANE REARRANGEMENT
- 5 November 1973
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 2 (11) , 1185-1188
- https://doi.org/10.1246/cl.1973.1185
Abstract
Isolation and characterization of a true intermediate in the adamantane rearrangement was made for the first time in the case of aluminum chloride-catalyzed isoraerization of either tricyclo[5.2.2.02,6]undecane (I) or tetramethylenenorbornane (II) to 1-methyladamantane, the intermediate in either case being tricyclo(5.3.1.03,8]undecane (III) as determined by 13C nmr spectroscopy.This publication has 11 references indexed in Scilit:
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