A novel series of heterotrinuclear complexes with a tris(dimethylglyoximato)metal(II) anion as bridging ligand. Structure of the FeIIICuIIFeIIIcomplex with S= 9/2 ground state

Abstract
A series of linear heterotrinuclear complexes with a tris(dimethylglyoximato) metal(II) as bridging ligand, [LFeIII{µ-(dmg)3MII}FeIIIL](ClO4)2(M = Zn, Cu, Ni, Co, Fe, Mn), where L represents the cyclic triamine 1,4,7-trimethyl-1,4,7-triazacyclononane, has been synthesized and characterized by X-ray crystallography and magnetic susceptibility measurements.
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