Synthesis, crystal structure and some derivatives of the chlorotris(tetramethylphospholyl)uranium
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1720-1721
- https://doi.org/10.1039/c39920001720
Abstract
Reaction of UCl4 with the potassium salt of the tetramethylphospholyl anion afforded the title compound, which has been transformed into the derivatives [U(η-C4Me4P)3X](X = H, Me, OPri); the trigonal crystal structure revealed that the three phospholyl ligands are pentahapto bonded to the uranium.Keywords
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