Binding ability of acetamide oxime with proton, copper(II), and dioxouranium(VI) in aqueous solutions
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 8,p. 1609-1611
- https://doi.org/10.1039/dt9860001609
Abstract
The equilibrium constant of acetamidoxime (acetamide oxime) with proton in aqueous solutions was determined using the potentiometric method. The compositions and stability constants of the complexes of this ligand with CuII and UVIO2 in aqueous solutions were also determined. Acetamidoxime forms 1 : 1 and 1 : 2 complexes with CuII and UVIO2. Furthermore, the UVIO2 complexes were found to be more stable than those of CuII; these characteristic properties of the ligand are discussed in relation to the recovery of uranium from sea water.Keywords
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