Crown thioether chemistry: synthesis and characterisation of bis(1,4,7-trithiacyclononane)silver(I) trifluoromethanesulphonate, an octahedral homoleptic thioether complex of Ag I showing unusually facile oxidation
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 950-951
- https://doi.org/10.1039/c39870000950
Abstract
1,4,7-Trithiacyclononane (9S3) reacts with soluble silver(I) salts to form [Ag(9S3)2]+, a monomeric complex that has a distorted octahedral structure and is readily oxidised to the silver(II) complex.Keywords
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