X-Ray structure of the hexa(µ2-arenethiolato-)tetra(arenethiolato)tetracobaltate(II) dianion, [(CoSPh)4(µ2-SPh)6]2–, a new tetrahedral tetracobalt thiolate cluster
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 18,p. 762-763
- https://doi.org/10.1039/c39750000762
Abstract
The unique molecular cluster complex [(CoSPh)4(µ2-SPh)6]2–(Me4N+ cation) contains an approximately Td Co4S10 core, the clustering of four tetrahedral {CoII-(µ2-SPh)3(SPh)} co-ordination units being a consequence of ligand bridging, not metal–metal bonding.Keywords
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