Redox reactions of metal carbonyls of group 5A
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1249-1250
- https://doi.org/10.1039/c39840001249
Abstract
Redox reaction of V(CO)6 with [Co(CO)4]–, [Mn(CO)5]–, [M2(CO)10]2–, or [M(η5-C5H5)(CO)3]–(M = Cr, Mo, W), or Co(η5-C5H5)2 occur rapidly at 25 °C and lower in hydrocarbons; on the other hand, V(CO)6 is oxidized to V(η5-C5H5)(CO)4 by Mn(η5-C5H5)2 or Ni(η5-C5H5)2 and the two-electron oxidation of [Nb(CO)6]– to the [Nb2X3(CO)8]–anion (X = Cl, Br, I, acetylacetonato), can be carried out using a number of oxidizing agents (HgII,CUII,CUIAgI, or FeIII).Keywords
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