Kinetics of OH Radicals as Determined by Their Absorption Spectrum VI. Attempt to Trace OH Radicals in the Thermal Hydrogen-Oxygen Reaction
- 1 January 1946
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 14 (1) , 16-18
- https://doi.org/10.1063/1.1724055
Abstract
The steady thermal reaction of hydrogen and oxygen at a pressure of 60 cm and a temperature in the region of 550° C was searched by absorption spectrum technique for free OH radicals. None were detected, although the apparatus would have been sensitive to an OH radical pressure of 4×10−4 mm. This negative result indicates that the OH radicals have a very short lifetime in the reacting mixture.Keywords
This publication has 10 references indexed in Scilit:
- The Dissociation of H2O into H+OHThe Journal of Chemical Physics, 1944
- Mechanism of the Thermal Reaction Between Hydrogen and OxygenThe Journal of Chemical Physics, 1942
- Two Bridge-Controlled Thyratron ThermostatsReview of Scientific Instruments, 1942
- The Thermal Reaction Between Hydrogen and Oxygen III. The Temperature Coefficient of the Steady Thermal ReactionThe Journal of Chemical Physics, 1941
- The Metropolitan Section: Minutes of the Meeting of November 15, 1940Physical Review B, 1940
- Kinetics of OH Radicals as Determined by Their Absorption Spectrum1 V. A Spectroscopic Determination of a Rate ConstantThe Journal of Chemical Physics, 1939
- On Abnormal Rotation of MoleculesPhysical Review B, 1934
- THE FORMATION OF HYDROGEN PEROXIDE FROM HYDROGEN AND OXYGENJournal of the American Chemical Society, 1931
- THE THERMAL HYDROGEN-OXYGEN COMBINATION. FORMATION OF HYDROGEN PEROXIDE, AND THE INFLUENCE OF SURFACE NATURE1Journal of the American Chemical Society, 1930
- THE ABSORPTION SPECTRUM AND DECOMPOSITION OF HYDROGEN PEROXIDE BY LIGHTJournal of the American Chemical Society, 1929