Steroid Studies. XXVII. A New Aromatization Reaction of the Homoannular Diene System. (1). On the Structure of the Phenolic Compound derived from 3β-Acetoxylanosta-5, 8-dien-7-one.
- 1 January 1961
- journal article
- Published by Pharmaceutical Society of Japan in CHEMICAL & PHARMACEUTICAL BULLETIN
- Vol. 9 (2) , 131-138
- https://doi.org/10.1248/cpb.9.131
Abstract
It was observed that the methyl group in the 19-position of 3β-acetoxylanosta-5, 8-dien-7-one (I) would be easily eliminated as methane and the B-ring was aromatized by treatment with zinc. The other chemical and photochemical behaviors of (I) were examined.Keywords
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