A Tetranuclear 3d−4f Single Molecule Magnet: [CuIILTbIII(hfac)2]2
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- 20 December 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (2) , 420-421
- https://doi.org/10.1021/ja037365e
Abstract
We report now the first single molecule magnet (SMM) consisting of d−f elements. The present study demonstrates that the synthesis of the d−f polynuclear molecule is a very promising approach to SMMs. (1) The d−f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.Keywords
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