E- and Z-aldimines
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 183
- https://doi.org/10.1039/c39720000183
Abstract
The detection of Z-aldimines in equilibrium with the E-isomers in some N-(9-anthrylidene)alkylamines is ascribed to a lone pair repulsion effect; the barriers to interconversion of the diastereomers of N-(9-anthrylidene)methylamine have been estimated by direct thermal stereomutation and by dymamic n.m.r.Keywords
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