Palladium catalysed intra- and inter-molecular coupling of vinyl halides. Regiospecific formation of 1,3-dienes

Abstract
Palladium catalysed coupling of vinyl bromides proceeds in good yield under mild conditions provided sufficient triarylphosphine and potassium carbonate are present to regenerate the active palladium(0) species; double bond isomerisation is not observed under these conditions.

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