Synthesis of aziridines by reduction of oximes and O-alkyl oximes with sodium dihydrobis-(2-methoxyethoxy)aluminate
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1294-1299
- https://doi.org/10.1039/p19740001294
Abstract
Reduction of aryl ketone oximes and their O-alkyl derivatives with sodium dihydrobis-(2-methoxyethoxy)aluminate, gives aziridines in up to 90% yield. Stereochemical relationships and mechanisms for the formation of amines and cis- and trans-disubstituted aziridines are discussed.Keywords
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