Ring Cleavage of Cyclic 2-Nitroketones by KF Catalyst: A General Synthesis of ω-Nitroacids and ω-Nitroesters
- 1 December 1986
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 16 (14) , 1781-1788
- https://doi.org/10.1080/00397918608057201
Abstract
Preparation of ω-nitroacids and ω-nitroesters has been achieved by ring cleavage of 2-nitrocycloalkanones, under basic condition (KF), in water (THF solution) or alcohol.Keywords
This publication has 19 references indexed in Scilit:
- A new synthesis of α-methylene carbonyl compoundsTetrahedron Letters, 1983
- Synthesis of 2-Nitroalkanols on Alumina Surfaces without Solvent: A Simple, Mild and Convenient MethodSynthesis, 1983
- A new route to 1,4 -diketones and its application to (z)-jasmone and dihydrojasmone synthesisTetrahedron, 1983
- A short synthesis of (−)-prostaglandin E1Tetrahedron Letters, 1983
- Regiospecific C-α Deuteration of Alkyl Ketones; A New Efficient Indirect ProcedureSynthesis, 1983
- Denitration of α-Nitroketones by Treatment of their Tosylhydrazones with Lithium Aluminium Hydride; New Applications of the Henry ReactionSynthesis, 1983
- Conjugate addition of alkyl groups to α,β-unsaturated sulfoxides via Michael addition of nitroparaffins and subsequent denitration with tributyltin hydrideTetrahedron Letters, 1982
- Palladium(0)-catalyzed allylic alkylation and amination of allylnitroalkanesJournal of the American Chemical Society, 1982
- A new synthetic method: Direct replacement of the nitro group by hydrogen or deuteriumTetrahedron Letters, 1981
- 3-Nitrocycloalkenones, synthesis and use as reverse affinity cycloalkynone equivalentsTetrahedron Letters, 1981