Kinetic Study of the Anodic Reaction at the Electrodic Interface α‐AgI(s)/I2(g), C
- 1 April 1977
- journal article
- research article
- Published by Wiley in Berichte der Bunsengesellschaft für physikalische Chemie
- Vol. 81 (4) , 384-388
- https://doi.org/10.1002/bbpc.19770810407
Abstract
The anodic evolution of Iodine from solid α‐AgI was studied in the solid‐state cell Ag/AgI/I2(g), Graphite at different I2‐pressures and temperatures. A single pulse galvanostatic technique was used. The kinetic parameters obtained allowed the postulation of a fast discharge‐slow recombination (at low coverage) reaction mechanism. A dependence of the exchange current density upon the iodine partial pressure was found and interpreted on the basis of the postulated mechanism. A sort of “anode effect” was found.Keywords
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