Synthesis of Single-Crystalline CoP Nanowires by a One-Pot Metal−Organic Route
- 27 October 2005
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (46) , 16020-16021
- https://doi.org/10.1021/ja055963i
Abstract
A simple one-pot method has been used to prepare uniform single-crystalline CoP nanowires with a high aspect ratio by the thermal-decomposition reaction of cobalt(II) acetylacetone with long-chain alkylphosphonic acid in the presence of hexadecylamine (HDA) and trioctylphosphine oxide (TOPO) at high temperature. The crystal morphology of the resulting nanowires can be influenced by the ratio of HDA and TOPO.Keywords
This publication has 29 references indexed in Scilit:
- Chemical Routes for Production of Transition‐Metal Phosphides on the Nanoscale: Implications for Advanced Magnetic and Catalytic MaterialsChemistry – A European Journal, 2004
- A General Methodology for the Synthesis of Transition Metal Pnictide Nanoparticles from Pnictate Precursors and Its Application to Iron−Phosphorus PhasesJournal of the American Chemical Society, 2003
- One‐Dimensional Nanostructures: Synthesis, Characterization, and ApplicationsAdvanced Materials, 2003
- A Reversible Solid-State Crystalline Transformation in a Metal Phosphide Induced by Redox ChemistryScience, 2002
- Reversible lithium uptake by CoP3 at low potential: role of the anionElectrochemistry Communications, 2002
- Structural Characterization of Tungsten Phosphide (WP) Hydrotreating Catalysts by X-ray Absorption Spectroscopy and Nuclear Magnetic Resonance SpectroscopyThe Journal of Physical Chemistry B, 2002
- Binary and Ternary Transition-Metal Phosphides as HDN CatalystsJournal of Catalysis, 2001
- Linearly Polarized Emission from Colloidal Semiconductor Quantum RodsScience, 2001
- Highly Luminescent Monodisperse CdSe and CdSe/ZnS Nanocrystals Synthesized in a Hexadecylamine−Trioctylphosphine Oxide−Trioctylphospine MixtureNano Letters, 2001
- The Phosphonation of Aromatic Compounds with Phosphoric Anhydride1Journal of the American Chemical Society, 1954