An octanuclear iridum carbonyl cluster based on two equivalent tetrahedral units. Synthesis and X-ray characterization of bis(tetraphenylphosphonium) hexa-µ-carbonylhexadecacarbonyl-ditetrahedro-octairidate (2–)
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 528-529
- https://doi.org/10.1039/c39810000528
Abstract
The reaction of Ir4(CO)12 with KOH in 1,2-dimethoxyethane, under nitrogen, yields the [Ir8(CO)22]2– anion, which has been shown by X-ray crystallography to contain an iridium double cluster based on two symmetry-equivalent tetrahedral subunits.Keywords
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