Enantioselective Synthesis of 16-Membered a,b,g,d-Unsaturated Diolide: A Model System in Elaiophylin
- 1 January 1987
- journal article
- research article
- Published by The Japan Institute of Heterocyclic Chemistry in HETEROCYCLES
- Vol. 25 (1) , 43-46
- https://doi.org/10.3987/s-1987-01-0043
Abstract
The synthesis of the entitled diolide (17) has been achieve starting from levoglucosan (1, 6-anhydro-.beta.-D-glucopyranose) (2) via the macrocyclization of the hydroxy acid (16) by reaction of mixed phosphoric anhydride procedure.Keywords
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