Many-Body Perturbation Calculation of the Indirect Spin-Spin Coupling Constant in HD Molecule
- 21 December 1970
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 25 (25) , 1695-1699
- https://doi.org/10.1103/physrevlett.25.1695
Abstract
The linked-cluster many-body perturbation approach has been applied to the study of indirect nuclear spin-spin coupling constant in HD molecule. The complete set of states used were the bound and continuum states of molecular ion with the internuclear separation appropriate to molecule. Our calculated value of through the Fermi contact interaction mechanism is +42.57 Hz in good agreement with the most recent experimental value of +42.7±0.7 Hz.
Keywords
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