The microwave spectrum of the H2D+ ion: The 22 ← 221 transition

Abstract
The 220 ← 221 transition of H2D+ was detected by using a dc discharge in a mixture of H2 and D2 with a hollow cathode cooled to liquid nitrogen temperature. The assignment was made on the basis of chemistry for production, the observed linewidth, and the lowering of the spectral intensity by the external magnetic field. The transition frequency was determined to be 155 987.185±0.037 MHz.

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