The First C4B6 Carbaborane
- 1 July 1984
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 23 (7) , 512-514
- https://doi.org/10.1002/anie.198405121
Abstract
A novel type of organocarbaborane, the nido‐cluster 2, was prepared from the “monomeric” organo‐closo‐carbaborane 1 using a redox method, which should be generally applicable. The positions of the ten skeletal atoms in 2 can be assigned by NMR spectroscopy. equation imageKeywords
This publication has 14 references indexed in Scilit:
- Two-dimensional boron-11-boron-11 nuclear magnetic resonance spectroscopy as a probe of polyhedral structure: application to boron hydrides, carboranes, metallaboranes, and metallacarboranesJournal of the American Chemical Society, 1984
- Moderne Pulsfolgen in der hochauflösenden NMR‐SpektroskopieAngewandte Chemie, 1983
- Crystal and molecular structure of an iron dihydrogen metallocarborane, [2,3-(CH3)2C2B4H4]2FeH2. Steric aspects of the oxidative fusion processInorganic Chemistry, 1979
- Iron-hydrogen and iron-cobalt metallocarboranes. Synthesis and chemistry of [(CH3)2C2B4H4]2FeIIH2 and a novel tetracarbon carborane system, (CH3)4C4B8H8Inorganic Chemistry, 1976
- Borverbindungen XXXIII1) Darstellung und Eigenschaften alkylierter 1,5‐Dicarba‐closopentaborane(5)European Journal of Organic Chemistry, 1975
- Four-carbon carboranes. Synthesis of tetra-C-methyltetracarbadodecaborane(12) and its metallocarborane derivativesJournal of the American Chemical Society, 1974
- Electrochemical oxidation of B12H122-Journal of the American Chemical Society, 1967
- Borverbindungen, XIIQuantitative Bestimmung verschiedener B‐Funktionen in organischen Borverbindungen durch Oxydation mit Trimethylamin‐N‐oxidEuropean Journal of Organic Chemistry, 1967
- Kinetics of Electrochemical Oxidative Coupling of Decahydroclovodecaborate(2-) in Acetonitrile1Journal of the American Chemical Society, 1966
- Organocarborane aus Alkyl-1-alkinylboranen durch HydroborierungenAngewandte Chemie, 1966