Stable cobalt(I) complexes of tetradehydrocorrins
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 453-454
- https://doi.org/10.1039/c39720000453
Abstract
Cyanation and nitration of cobalt(II) tetradehydrocorrin salts yield cobalt(III) derivatives which can be converted readily into crystalline neutral cobalt(I) complexes; these substituted cobalt(I) tetradehydrocorrins are reversibly oxidised to stable cobalt(II) complex at potentials anodic to the oxidation potential of the unsubstituted cobalt(I) complex.Keywords
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