Self-Assembly of a Polar Open-Framework Uranyl Vanadyl Hexaoxoiodate(VII) Constructed Entirely from Distorted Octahedral Building Units in the First Uranium Hexaoxoiodate: K2[(UO2)2(VO)2(IO6)2O]·H2O
- 4 March 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (7) , 2179-2181
- https://doi.org/10.1021/ic026290x
Abstract
The reaction of UO(3) with V(2)O(5) and KIO(4) under mild hydrothermal conditions produces K(2)[(UO(2))(2)(VO)(2)(IO(6))(2)O].H(2)O (1) in the form of orange acicular crystals. The structure of 1 consists of UO(6), VO(6), and IO(6) distorted octahedra that are assembled into a polar, open-framework structure. The distorted VO(6) and IO(6) octahedra edge-share to form chains that run down the c-axis. Each VO(6) octahedron also shares a vertex with an adjacent vanadium atom to link the chains together into a ribbon. The IO(6) units also partake in corner-sharing with the UO(6) units to create interconnected elliptical tubes. The major channels in 1 are filled with K(+) cations and water molecules. The polarity of this compound is caused by alignment of distorted vanadyl hexaoxoiodate ribbons and UO(6) trapezoidal bipyramids resulting in a large second-harmonic generation response of 300 times that of alpha-quartz. Crystallographic data: 1, orthorhombic, space group Pba2, a = 9.984(2) A, b = 16.763(3) A, c = 4.977(1) A, Z = 4 (T = 193 K).Keywords
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