SCHIFF BASE COMPLEXES OF OXOCATIONS Part II Oxovanadium(IV) complexes with tetradentate optically active Schiff bases
- 1 May 1974
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 3 (4) , 319-332
- https://doi.org/10.1080/00958977408075868
Abstract
The synthesis and properties of oxovanadium(IV) complexes with tetradentate Schiff bases obtained by condensation of two moles of acetylacetone, trifluoroacetylacetone, salicylaldehyde and its 5-chloro and 5-nitro derivatives, with optically active 1,2-diamines, namely (+) propylenediamine, (+) and meso butanediamine, (+) and meso cyclohexanediamine, (-) and meso stilbenediamine, are described. The infrared, circular dichroism and electronic spectra are reported and discussed. The factors influencing the formation of hexacoordinate adducts with donor bases are also discussed.Keywords
This publication has 28 references indexed in Scilit:
- Schiff base complexes of oxocations—I Uranyl complexes with tetradentate optically active Schiff bases of salicylaldehydeJournal of Inorganic and Nuclear Chemistry, 1972
- Five-coordinate compounds…-IV: Synthesis and properties of [o…-OC6H4CHNCH2C(CH3)2NCHC6H4O…-o]VOJournal of Inorganic and Nuclear Chemistry, 1970
- Crystal and molecular structure of N,N'-ethylenebis(acetylacetoneiminato)oxovanadium(IV)Inorganic Chemistry, 1970
- Application of exciton theory to the determination of the absolute configurations of inorganic complexesAccounts of Chemical Research, 1969
- Spectral studies of β-ketoenolate complexes of oxovanadium(IV)Journal of Inorganic and Nuclear Chemistry, 1967
- Five-co-ordinate compounds—IIIJournal of Inorganic and Nuclear Chemistry, 1965
- Five-co-ordinate compounds-II: Studies on β-diketo and β-ketoimino complexes of oxovanadium (IV) ionJournal of Inorganic and Nuclear Chemistry, 1965
- Thermodynamics of Coordination to an Unsolvated Position in Vanadyl AcetylacetonateJournal of the American Chemical Society, 1965
- Sulfoxides as Ligands. I. A Preliminary Survey of Methyl Sulfoxide ComplexesJournal of the American Chemical Society, 1960
- Inner Complex Chelates. II. Analogs and Polar Substituted Analogs of Bisacetylacetoneëthylenediimine and its Metal Chelates1,2Journal of the American Chemical Society, 1959