Studies on the Medicinal Resources. XVIII

Abstract
Extraction of fresh leaves of Lonicera japonica THUNB. with methanol and treatment of the methanolic extract with lead acetate afforded pale yellow microneedles, m.p. 218°, [α]D19 -83.5°, C27H30O15⋅2H2O, in 0.01% yield. This substance was named lonicerin. Hydrolysis of lonicerin with 5% sulfuric acid gave luteolin, rhamnose, and glucose. Permethylation of lonicerin followed by hydrolysis afforded 3′, 4′, 5-tri-O-methylluteolin. It follows, therefore, that the sugar is bonded at the 7-position and that lonicerin is luteolin 7-rhamnoglucoside.

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