Dimethyl(phenylchalkogeno)bismutane — Moleküle mit Bismut-Schwefel, -Selen und -Tellur-Bindungen / Dimethyl(phenylchalcogeno)bismuthanes — Molecules with Bismuth-Sulfur, -Selenium and -Tellurium Bonds
Open Access
- 1 December 1984
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 39 (12) , 1668-1670
- https://doi.org/10.1515/znb-1984-1208
Abstract
Dimethyl(phenylchalcogeno)bismuthanes of the general formula (CH3)2BiEC6H5(E = S, Se, Te), the first m olecules with a Bi -Se or a Bi-Te-bond, respectively, were synthesized in good yields by reactions of tetramethyldibismuthane and diphenyldichalcogenides. At room temperature - these thermolabile compounds react quantitatively - with increasing rate in the series S-Se-Te to give CH3Bi(EC6H5)2 and Bi(CH3)3.Keywords
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