The oxidation of trimethylsilylated amides to hydroxamic acids
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 10,p. 2481-2487
- https://doi.org/10.1039/p19790002481
Abstract
A method for the oxidation of trimethylsilylated amides to the corresponding hydroxamic acids is described. The method utilises aprotic oxidants, based on MoV peroxides and has been demonstrated for the oxidation of a variety of secondary amides. The oxidation is particularly efficient for aromatic amides and has been applied to the synthesis of herbicides of the 2,4-dihydroxybenzoxazinone class.This publication has 6 references indexed in Scilit:
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