High esterolytic activity of a novel water-soluble polymer catalyst imprinted by a transition-state analogue
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 2143-2144
- https://doi.org/10.1039/c39950002143
Abstract
A novel water-soluble polymer catalyst containing a L-histidyl group as a catalytic site, prepared by imprinting of a transition-state analogue of phenyl 1-benzyloxycarbonyl-3-methylpentyl phosphonate, accelerates the substrate-specific esterolysis of p-nitrophenyl N-(benzyloxycarbonyl)-L-leucinate (Z-L-Leu-PNP) in 10 vol% Me2O–Tris buffer (pH 7. 15) at 293–308 K.Keywords
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