Structure and Magnetic Properties of a Dodecanuclear Twisted-Ring Iron(III) Cluster
- 3 May 1999
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 38 (9) , 1295-1297
- https://doi.org/10.1002/(sici)1521-3773(19990503)38:9<1295::aid-anie1295>3.0.co;2-l
Abstract
An unprecedented nonplanar structure characterizes the complex [Fe(OCH3)2(dbm)]12 (on the left in the picture), which contains the largest cyclic ferric cluster yet reported with chemically equivalent bridging units. It is made up of twelve high-spin, antiferromagnetically coupled iron(III) centers and neatly reacts with NaI or LiI templates in organic solution to give hexairon(III) coronates (right). Fe=•, O=○, NaI or LiI=• Hdbm=dibenzoylmethane.This publication has 0 references indexed in Scilit: