A Silatetragallane—Classical Heterobicyclopentane orcloso-Polyhedron?
- 4 September 1998
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 37 (16) , 2209-2211
- https://doi.org/10.1002/(sici)1521-3773(19980904)37:16<2209::aid-anie2209>3.0.co;2-3
Abstract
Classical and nonclassical can be used to describe the bonding in the polyhedral Ga4Si framework of the silagallanate ion [Me3SiSi{GaSi(SiMe3)3}3GaSiMe3]− (the GaSi framework is depicted in the picture). This is the result of density functional calculations that were carried out on model compounds. The cluster was obtained by ultrasonication of gallium and iodine and subsequent reaction with (Me3Si)3Li(thf)3.This publication has 0 references indexed in Scilit: