Oxarhodaborane chemistry: the formation of [µ-9,9′-O-{5-(η5-C5Me5)-nido-5-RhB9H12}2] and [7-(η5-C5Me5)-10-(NEt3)-nido-7, 12-RhOB10H10] from [nido-(η5-C5Me5)RhB10H13Cl]
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1692-1694
- https://doi.org/10.1039/c39900001692
Abstract
Chromatography in air on silica of the nido eleven-vertex metallaborane [(η5-C5Me5)RhB10H13Cl]2, yields the µ-9,9′-oxo-bridged bis(nido-5-rhodadecaboranyl) species [{(η5-C5Me5)RhB9H12}2O]3, whereas treatment with NEt3 before exposure to air and chromatography on silica results in the novel contiguous nido twelve-vertex oxarhodadecaborane [7-(η5-C5Me5)10-(NEt3)-nido-7,12-RhOB10H10]4.Keywords
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