Energy levels of paramagnetic ions: Algebra. II
- 1 November 1969
- journal article
- research article
- Published by Wiley in International Journal of Quantum Chemistry
- Vol. 3 (6) , 795-822
- https://doi.org/10.1002/qua.560030606
Abstract
The correspondence rules between the algebra of coupling coefficients of the special unitary group SU(2) and the associated algebra of a subgroup G of SU(2) are presented. The matrix elements of the irreducible representations of G are written in a convenient quantization scheme and different relations between these matrix elements and the Clebsch‐Gordan coefficients of G are derived. Such a formalism is appropriate for numerous spectroscopic problems. As an example, it is applied to crystal field theory and electron paramagnetic resonance. General formulas from which a large number of results are rederived and generalized in a straightforward fashion are given. Numerical values of coupling coefficients for the tetragonal and cubic groups are listed in the Appendix.Keywords
This publication has 34 references indexed in Scilit:
- The internal symmetry crossing matrices for an arbitrary compact groupAnnals of Physics, 1968
- Ionic and paramagnetic energy levels algebraJournal of Molecular Spectroscopy, 1968
- Symmetry Properties of the 3j-Symbols for an Arbitrary GroupJournal of Mathematical Physics, 1966
- Racah Algebra for an Arbitrary GroupJournal of Mathematical Physics, 1965
- Tensor operators under semi-simple groupsMathematical Proceedings of the Cambridge Philosophical Society, 1961
- On the Absorption Spectra of Complex Ions IV. The Effect of the Spin-orbit Interaction and the Field of Lower Symmetry on d electrons in Cubic FieldJournal of the Physics Society Japan, 1958
- On the Absorption Spectra of Complex Ions. IJournal of the Physics Society Japan, 1954
- Theory of Complex Spectra. IVPhysical Review B, 1949
- Theory of Complex Spectra. IIIPhysical Review B, 1943
- Theory of Complex Spectra. IIPhysical Review B, 1942