A fluxional arachno-1 -metallapentaborane, [1,1,1 -(CO)(PMe3)2(1-IrB4H9)]
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 2,p. 481-483
- https://doi.org/10.1039/dt9820000481
Abstract
The reaction of nido-B9H12 – with trans-[Ir(CO)Cl(PMe3)2] yields several new compounds, among which is the pale yellow arachno-1-metallapentaborane [1,1,1-(CO)(PMe3)2(1-IrB4H9)]. This compound bears the same relation to arachno-B5H11 as nido-[1,1,1-(CO)3(1-FeB4H8)] bears to nido-B5H9. The fluxionality of the compound and its 1H, 11B, and 31P n.m.r. spectra are described.Keywords
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