Catalytic and asymmetric oxidation of sulphides with iron complexes of chiral ‘twin coronet’ porphyrins
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1378-1380
- https://doi.org/10.1039/c39900001378
Abstract
Iron porphyrins that are modified on both faces by chiral binaphthalenes catalysed asymmetric oxidation of sulphides in fair to good enantiomeric excesses and excellent turnover numbers of the catalysts in the presence of 1-methylimidazole.Keywords
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