Mechanisms in the chlorinolysis of sulfinyl chlorides
- 1 March 1984
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 62 (3) , 610-614
- https://doi.org/10.1139/v84-103
Abstract
The successful synthesis and chlorinolysis of α-mercaptodimefhyl sulfone have provided additional support for our contention that Pummerer rearrangements may occur during the chlorinolyses of α-sulfonyl sulfinyl chlorides. Further exploration of chlorinolyses of α-sulfonyl systems has uncovered the first observations of CS bond cleavage during the chlorinolyses of (i) a sulfinyl chloride and (ii) a sulfinate ester.Keywords
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