Vinylsulfonyl Chloride, a Ketene Equivalent for the Intramolecular Diels-Alder Reaction
- 1 January 1992
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1992 (12) , 985-987
- https://doi.org/10.1055/s-1992-21556
Abstract
A completely regioselective and highly diastereoselective formal [4+2]-cycloaddition of ketene to 1,3-dienes bearing hydroxylated side chains is achieved by intramolecular Diels-Alder reaction of their vinylsulfonates followed by oxidative desulfurization.Keywords
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