Synthesis of 5- and 6-methylene-2-norbornanones
Open Access
- 15 April 1978
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 56 (8) , 1134-1139
- https://doi.org/10.1139/v78-191
Abstract
The syntheses of 4,4,6-trimethyl-5-methylene-2-norbornanone (5a), 6,6-dimethyl-2-methyl- ene-2-norbornanone (5b), 5-methylene-2-norbornanone (5c), and 6-methylene-2-norbornanone (11) are described. An unusual extended Grob-type cleavage of 6-ethylenedioxy-exo-2-methyl-endo-2-norbornanol (13d) to 2-chioroethyl (3-methyl-3-cyclopentenyl)acetate (17) is documented.Keywords
This publication has 0 references indexed in Scilit: