Diastereoselective Synthesis of Triacetyl-L-erythro-C18-sphingosine.

Abstract
A new stereoselective synthetic route to triacetyl-L-erythro-C18-sphingosine has been developed by the combination of diastereoselective addition of thiophenol to chiral olefins and subsequent intramolecular substitution of the corresponding sulfonium group.

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