New Methods for the Synthesis of P-Chirogenic Diphosphines: An Application to the Development of an Improved Asymmetric Variation of the Rh(I)-Catalyzed [4 + 2] Cycloaddition
- 1 January 2001
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 2001 (15) , 2341-2347
- https://doi.org/10.1055/s-2001-18432
Abstract
A series of new P-chirogenic diphosphines has been prepared by efficient and complementary synthetic procedures. The utilization of a series of these bidentate ligands possessing steric linker variations and a conserved P-chirogenic domain in an asymmetric variation of the Rh(I)-catalyzed [4 + 2] enediene cycloaddition is described.Keywords
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