Hydroxylation of Alkanes Catalyzed by Manganese Tetraphenylporphyrin Immobilized on Imidazole-modified Silica Gel
- 1 March 1989
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (3) , 419-420
- https://doi.org/10.1246/cl.1989.419
Abstract
Immobilization of Mn(TPP)Cl (TPP = tetraphenylporphyrin) onto 3-imidazolylpropyl-modified SiO2 resulted in enhancement of its activity for hydroxylation of cyclohexane; the support prevented the complex from forming a dimer leading to oxidative destruction.Keywords
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