Synthesis and Structural Characterization of a Terminal Hydroxide Containing Alumoxane via Hydrolysis of Aluminum Hydrides
- 30 January 2004
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 43 (4) , 1217-1219
- https://doi.org/10.1021/ic0351803
Abstract
A novel terminal hydroxide containing dinuclear alumoxane LAl(OH)OAlL(OCH=N-tBu) (3; L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) was prepared by treatment of aluminum dihydride LAlH2 (1) and tert-butyl isocyanate in the presence of trace amounts of water and alternatively from 1 and LAlH(OCH=N-tBu) (2) with water. Compound 2 was obtained from the reaction of 1 and tert-butyl isocyanate.Keywords
This publication has 11 references indexed in Scilit:
- Is Water a Friend or Foe in Organometallic Chemistry? The Case of Group 13 Organometallic Compounds†Accounts of Chemical Research, 2001
- Synthesis, Structure, and Reactivity of β-Diketiminato Aluminum ComplexesOrganometallics, 1998
- [Al5(tBu)5(.mu.3-O)2(.mu.3-OH)2(.mu.-OH)2(.mu.-O2CPh)2]: A Model for the Interaction of Carboxylic Acids with BoehmiteOrganometallics, 1995
- Tert-Butylaluminum Hydroxides and Oxides: Structural Relationship between Alkylalumoxanes and Alumina GelsOrganometallics, 1994
- Hydrolysis of tri-tert-butylaluminum: the first structural characterization of alkylalumoxanes [(R2Al)2O]n and (RAlO)nJournal of the American Chemical Society, 1993
- Decomposition of high-oxygen content organoaluminum compounds. The formation and structure of the [Al7O6Me16]- anionOrganometallics, 1983
- „Lebende Polymere” bei Ziegler-Katalysatoren extremer ProduktivitätAngewandte Chemie, 1980
- Bis(dialkylaluminum) oxide from lithium dialkylaluminates and dialkylaluminum chloridesInorganic Chemistry, 1973
- The partial hydrolysis of ethylalane compoundsJournal of the American Chemical Society, 1968
- Stereospecific polymerization of acetaldehyde. Part IJournal of Polymer Science, 1962